Let's tackle the questions one by one:
1. **A Barcelona playmaker back in the days.**
Answer: **Xavi** (X)
2. **The German goalkeeper that didn't play due to Neuer.**
Answer: **Ter Stegen** (T)
3. **Best Premier League club to never win the Champions League.**
Answer: **Newcastle United** (N)
4. **Name of France's first division team.**
Answer: **Ligue 1** (L)
5. **Best ever goalkeeper that wore a hat.**
Answer: